A review of recent developments of metal-organic frameworks as combined biomedical platforms over the past decade.

Catalysts played a crucial role in advancing modern human civilization, from ancient times to the industrial revolution. Due to high cost and limited availability of traditional catalysts, there is a need to develop cost-effective, high-activity, and nonprecious metal-based electrocatalysts. Metal-organic frameworks (MOFs) have emerged as an ideal candidate for heterogeneous catalysis due to their physicochemical properties, hybrid inorganic/organic structures, uncoordinated metal sites, and accessible organic sections. MOFs are high nanoporous crystalline materials that can be used as catalysts to facilitate polymerization reactions. Their chemical and structural diversity make them effective for various reactions compared to traditional catalysts. MOFs have been applied in gas storage and separation, ion-exchange, drug delivery, luminescence, sensing, nanofilters, water purification, and catalysis. The review focuses on MOF-enabled heterogeneous catalysis for value-added compound production, including alcohol oxidation, olefin oligomerization, and polymerization reactions. MOFs offer tunable porosity, high spatial density, and single-crystal XRD control over catalyst properties. In this review, MOFs were focused on reactions of CO2 fixation, CO2 reduction, and photoelectrochemical water splitting. Overall, MOFs have great potential as versatile catalysts for diverse applications in the future.

MOFs as Versatile Catalysts: Synthesis Strategies and Applications in Value-Added Compound Production.

The synthetic strategies of COFs, for Drug delivery, Photo/Sono-dynamic, Photo/ Microwave thermal and Combined Therapy

In recent years, covalent organic framework (COFs) has emerged as a new class due to the high structural designability and functional tunability. The purpose of this review article is to present the latest and most significant applications with photo-responsive COFs as photo-catalysts. At the first, the subjects containing of bottom-up, post modification and blending techniques were investigated to form composites based on COFs. This review provided a comprehensive overview of the synthesis strategy of COFs. There are the synthesis strategies to synthesize COFs, including solvothermal, microwave, the microwave-assisted solvothermal synthesis, sonochemical, ionothermal, mechanochemical, light promoted and one-pot methods. Additionally, based on three methods including reactive skeletons, reactive pendant groups and reactive metals, COF-based catalysts were designed to apply in various fields. So, it confirmed that photocatalytic performance as metal-free and metal-COFs photocatalysts was developed by doping metal ions and metal NPs. In this review, some viewpoints of metal- COF photocatalysts as heterogeneous photocatalysts, discussed the applications in reactions' products, Suzuki-Miyaura reactions, Heck cross-coupling reaction, olefins reactions, energy conversion. Additionally, in the review, the photo-based applications of the COFs, MOFs@COFs' composites and metal composites based on COFs were investigated in photo-degradation of pollutants. At last, COF was used as a photocatalytic nicotinamide cofactor regeneration. 

Recent progress in designing heterogeneous COFs with the photocatalytic performance

Synthesis, Characterization of Fe3O4@SiO2@APTS-OCS as Adsorbent for Hg2+, Dye and Drug Adsorption: Theorical Calculations

Cobalt-based electroactive compounds: synthesis and their electrochemical and pseudocapacitance performance

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Cobalt-based electroactive compounds: synthesis and their electrochemical and pseudocapacitance performance