Dmitry G. Gusev
Wilfrid Laurier University
4 Papers
45 Citations
Dmitry G. Gusev is an academic researcher from Wilfrid Laurier University. The author has contributed to research in topics: Metalation & Carbene. The author has an hindex of 3, co-authored 4 publications. Previous affiliations of Dmitry G. Gusev include Queen's University.
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Papers
Carbanionic Friedel-Crafts equivalents. regioselective directed ortho and remote metalation-C-N cross coupling routes to acridones and dibenzo[b,f]azepinones.
TL;DR: Carbanion-mediated general regioselective routes to acridones 4 and dibenzo[b,f]azepinones 20 are described and low energy conformations for compounds 18b and 23 indicate that the cyclization reactions are under kinetic control.
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N,N′‐Diamidoketenimines via Coupling of Isocyanides to an N‐Heterocyclic Carbene.
TL;DR: First reaction of the heterocyclic carbene (I) with isocyanides yielding ketenimines like (III) is reported in this paper, where the first reaction is described as follows:
3
Carbanionic Friedel—Crafts Equivalents. Regioselective Directed ortho and Remote Metalation—C—N Cross Coupling Routes to Acridones and Dibenzo[b,f]azepinones.
TL;DR: Carbanion-mediated general regioselective routes to acridones 4 and dibenzo[b,f]azepinones 20 (Table 4) are described in this paper.
N,N'-diamidoketenimines via coupling of isocyanides to an N-heterocyclic carbene.
TL;DR: DFT analyses revealed that the carbene exhibits a unique, low-lying LUMO, which may explain the atypical reactivity observed in the new class of ketenimines observed.