Davide Rigo
Ca' Foscari University of Venice
5 Papers
10 Citations
Davide Rigo is an academic researcher from Ca' Foscari University of Venice. The author has contributed to research in topics: Isopropenyl acetate & Catalysis. The author has an hindex of 2, co-authored 5 publications.
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Papers
Diversified upgrading of HMF via acetylation, aldol condensation, carboxymethylation, vinylation and reductive amination reactions
TL;DR: In this article, a tandem protocol of acetylation/transcarbonation and aldol condensation was designed to synthesize a variety of HMF-derived α,β-unsaturated carbonyl compounds.
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Acid-Catalyzed Reactions of Isopropenyl Esters and Renewable Diols: A 100% Carbon Efficient Transesterification/Acetalization Tandem Sequence, from Batch to Continuous Flow
TL;DR: A new acid-catalyzed tandem sequence was investigated for the upgrading of renewable 1,2-diols such as propylene glycol (PG), with isopropenyl esters as mentioned in this paper.
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Concatenated batch and continuous flow procedures for the upgrading of glycerol-derived aminodiols via N-acetylation and acetalization reactions
TL;DR: In this article, an unprecedented two-step sequence was designed by combining batch and continuous flow protocols for the upgrading of two aminodiol regioisomers derived from glycerol, i.e., 3-amino-1,2-propanediol (serinol), under batch conditions, at 80-90 °C, both substrates were quantitatively converted into the corresponding amides through a catalyst-free N-acetylation reaction mediated by an innocuous enol ester as isopropenyl acetate (iPAc).
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Diethylene Glycol/NaBr Catalyzed CO2 Insertion into Terminal Epoxides: From Batch to Continuous Flow
TL;DR: In this paper, a continuous-flow (CF) reaction protocol was proposed for CO2 insertion on terminal epoxides (styrene oxide, 1,2-epoxyhexane and butyl glycidyl ether) in a binary homogeneous mixture comprising NaBr as the nucleophilic catalyst and diethylene glycol (DEG) as both solvent and catalyst activator (cation coordinating agent).
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A transesterification–acetalization catalytic tandem process for the functionalization of glycerol: the pivotal role of isopropenyl acetate
TL;DR: In this paper, a tandem sequence was implemented by which a pool of innocuous reactants (isopropenyl acetate, acetic acid and acetone) allowed upgrading of glycerol through selective acetylation and acetalization processes.
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