In this study, nano-sized mesoporous carbon-supported HG2 and magnetic γ-Fe2O3 nanoparticles were encapsulated within calcium alginate gels using a one-pot procedure. Mesoporous carbon within hydrophilic alginate shell provided hydrophobic compartments...

Encapsulation of Hoveyda-Grubbs 2nd Generation Catalyst in Magnetically Separable Alginate/Mesoporous Carbon Beads for Olefin Metathesis Reactions in Water

Selective Molecular Recognition, C-H Bond Activation, and Catalysis in Nanoscale Reaction Vessels Dorothea Fiedler, Dennis H. Leung, Robert G. Bergman, Kenneth N. Raymond Chemical Sciences Division, Lawrence Berkeley National Laboratory, and Department of Chemistry, University of California, Berkeley, California 94720 Addresses Dorothea Fiedler Department of Chemistry University of California, Berkeley, CA 94720-1460, USA Fax: (+1) 510-642-7714 Dennis H. Leung Department of Chemistry University of California, Berkeley, CA 94720-1460, USA Fax: (+1) 510-642-7714 Robert G. Bergman Department of Chemistry University of California, Berkeley, CA 94720-1460, USA Fax: (+1) 510-642-7714 E-mail: bergman@cchem.berkeley.edu Kenneth N. Raymond Department of Chemistry University of California, Berkeley, CA 94720-1460, USA Fax: (+1) 510-486-5283 E-mail: raymond@socrates.berkeley.edu Biographical Information Dorothea Fiedler was born in Hamburg, Northern Germany, in 1978. She went to college at the University of Wurzburg, Southern Germany, and received her Diplom in chemistry

Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels

A modular and efficient synthetic platform for the construction of supramolecular mono-telechelic polymers

Hydrocarboxylation of C═C Bonds in Polycyclooctene: Progress Toward Valorization of Waste Polyolefins

Processive catalysts remain attached to a substrate and perform multiple rounds of catalysis. They are abundant in nature. This review highlights artificial processive catalytic systems, which can be divided into (A) catalytic rings that move along a polymer chain, (B) catalytic pores that hold polymer chains and decompose them, (C) catalysts that remain attached to and move around a cyclic substrate via supramolecular interactions, and (D) anchored catalysts that remain in contact with a substrate via multiple catalytic interactions (see frontispiece).

Artificial Processive Catalytic Systems.

Provided are: a polymer material that has a polysiloxane backbone and that has excellent mechanical properties and high hygroscopicity; and a production method for the polymer material.　The present invention is a polymer material having a polysiloxane backbone, wherein the polysiloxane backbone has, at a side chain thereof, a constituent unit represented by general formula (1): -R1-RH (in formula (1), R1 represents NH or O, and RH represents a host group). The host group is a monovalent group in which a hydrogen atom or a hydroxy group is removed from a cyclodextrin or a cyclodextrin derivative. The cyclodextrin derivative has a structure obtained by substituting the hydrogen atom of at least one hydroxy group possessed by a cyclodextrin, with at least one group selected from the group consisting of hydrocarbon groups, acyl groups, and -CONHR (R represents a methyl group or an ethyl group).

Polymer material and production method therefor

Preparation and activity of ruthenium catalyst based on β-cyclodextrin for ring-opening metathesis polymerization

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Polymer material and production method therefor

Preparation and activity of ruthenium catalyst based on β-cyclodextrin for ring-opening metathesis polymerization