Tailored design of high-performance nanofiltration (NF) membranes is desirable because the requirements for membrane performance, particularly ion/salt rejection and selectivity, differ among the various applications of NF technology ranging from drinking water production to resource mining. However, this customization greatly relies on a comprehensive understanding of the influence of membrane fabrication methods and conditions on membrane properties and the relationships between the membrane structural and physicochemical properties and membrane performance. Since the inception of NF, much progress has been made in forming the foundation of tailored design of NF membranes and the underlying governing principles. This progress includes theories regarding NF mass transfer and solute rejection, further exploitation of the classical interfacial polymerization technique, and development of novel materials and membrane fabrication methods. In this critical review, we first summarize the progress made in controllable design of NF membrane properties in recent years from the perspective of optimizing interfacial polymerization techniques and adopting new manufacturing processes and materials. We then discuss the property-performance relationships based on solvent/solute mass transfer theories and mathematical models, and draw conclusions on membrane structural and physicochemical parameter regulation by modifying the fabrication process to improve membrane separation performance. Next, existing and potential applications of these NF membranes in water treatment processes are systematically discussed according to the different separation requirements. Finally, we point out the prospects and challenges of tailored design of NF membranes for water treatment applications. This review bridges the long-existing gaps between the pressing demand for suitable NF membranes from the industrial community and the surge of publications by the scientific community in recent years. 

Tailored design of nanofiltration membranes for water treatment based on synthesis–property–performance relationships

Nanofiltration (NF) membranes have been widely applied in many important environmental applications, including water softening, surface/groundwater purification, wastewater treatment, and water reuse. In recent years, a new class of piperazine (PIP)-based NF membranes featuring a crumpled polyamide layer has received considerable attention because of their great potential for achieving dramatic improvements in membrane separation performance. Since the report of novel crumpled Turing structures that exhibited an order of magnitude enhancement in water permeance ( Science 2018, 360 (6388), 518-521), the number of published research papers on this emerging topic has grown exponentially to approximately 200. In this critical review, we provide a systematic framework to classify the crumpled NF morphologies. The fundamental mechanisms and fabrication methods involved in the formation of these crumpled morphologies are summarized. We then discuss the transport of water and solutes in crumpled NF membranes and how these transport phenomena could simultaneously improve membrane water permeance, selectivity, and antifouling performance. The environmental applications of these emerging NF membranes are highlighted, and future research opportunities/needs are identified. The fundamental insights in this review provide critical guidance on the further development of high-performance NF membranes tailored for a wide range of environmental applications.

Nanofiltration Membranes with Crumpled Polyamide Films: A Critical Review on Mechanisms, Performances, and Environmental Applications.

Ultrathin membranes are at the forefront of membrane research, offering great opportunities in revolutionizing separations with ultrafast transport. Driven by advanced nanomaterials and manufacturing technology, tremendous progresses are made over the last 15 years in the fabrications and applications of sub‐50 nm membranes. Here, an overview of state‐of‐the‐art ultrathin membranes is first introduced, followed by a summary of the fabrication techniques with an emphasis on how to realize such extremely low thickness. Then, different types of ultrathin membranes, categorized based on their structures, that is, network, laminar, or framework structures, are discussed with a focus on the interplays among structure, fabrication methods, and separation performances. Recent research and development trends are highlighted. Meanwhile, the performances and applications of current ultrathin membranes for representative separations (gas separation and liquid separation) are thoroughly analyzed and compared. Last, the challenges in material design, structure construction, and coordination are given, in order to fully realize the potential of ultrathin membranes and facilitate the translation from scientific achievements to industrial productions.

Ultrathin Membranes for Separations: A New Era Driven by Advanced Nanotechnology

Surface characterization of thin-film composite membranes using contact angle technique: Review of quantification strategies and applications.

In recent decades, nanofiltration (NF) is considered as a promising separation technique to produce drinking water from different types of water source. In this paper, we comprehensively reviewed the progress of NF-based drinking water treatment, through summarizing the development of materials/fabrication and applications of NF membranes in various scenarios including surface water treatment, groundwater treatment, water reuse, brackish water treatment, and point of use applications. We not only summarized the removal of target major pollutants (e.g., hardness, pathogen, and natural organic matter), but also paid attention to the removal of micropollutants of major concern (e.g., disinfection byproducts, per- and polyfluoroalkyl substances, and arsenic). We highlighted that, for different applications, fit-for-purpose design is needed to improve the separation capability for target compounds of NF membranes in addition to their removal of salts. Outlook and perspectives on membrane fouling control, chlorine resistance, integrity, and selectivity are also discussed to provide potential insights for future development of high-efficiency NF membranes for stable and reliable drinking water treatment.

/pdf/nanofiltration-for-drinking-water-treatment-a-review-1o6pu2b23v.pdf

Nanofiltration for drinking water treatment: a review.

This paper investigates the relationship between roughness and fouling in reverse osmosis (RO) through specially designed experimental protocols and computational fluid dynamics (CFD) studies. Conv...

Understanding the Roughness-Fouling Relationship in Reverse Osmosis: Mechanism and Implications.

Surface patterns provide a chemical-free approach to reduce fouling by mimicking nature and are yet limited by their complicated fabrication procedures. Here, we report readily scalable methods to create sub-micrometer- and millimeter-scale patterns on membrane surfaces for low-scaling desalination, with a focus on the antiscaling mechanism. Specifically, a robust polyethylene (PE) lithium battery separator prepared from melt casting and stretching has been used as the support for nanofiltration (NF), giving micrometer-scale crumples on the surface. Then, the PENF membrane is imprinted by a permeate spacer during tests, leading to millimeter-scale patterns. Two types of experiments are designed to give insights into the impact of surface structure on scaling in NF processes, including (1) comparisons of smooth surfaces and surfaces with nanometer-, micrometer-, and millimeter-scale features and (2) no-stirring dead-end tests and crossflow tests. It has been found that micrometer-scale patterns are resistant to scaling through both spatial and hydrodynamic effects, and millimeter-scale patterns are also effective in reducing scaling solely due to hydrodynamic effects. Computational fluid dynamics (CFD) simulation gives further explanations. In addition, organic and microbial fouling has been studied to give implications for future membrane engineering.

Macropatterning of Microcrumpled Nanofiltration Membranes by Spacer Imprinting for Low-Scaling Desalination

We report the development of double-cross-linked thin film nanocomposite (TFN) hollow fiber membranes based on polyhedral oligomeric silsesquioxane (POSS) at scalable fabrication conditions for ult...

Double Cross-Linked POSS-Containing Thin Film Nanocomposite Hollow Fiber Membranes for Brackish Water Desalination via Reverse Osmosis

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Papers

Understanding the Roughness-Fouling Relationship in Reverse Osmosis: Mechanism and Implications.

Macropatterning of Microcrumpled Nanofiltration Membranes by Spacer Imprinting for Low-Scaling Desalination

Double Cross-Linked POSS-Containing Thin Film Nanocomposite Hollow Fiber Membranes for Brackish Water Desalination via Reverse Osmosis