Owing to their immense potential in energy conversion and storage, catalysis, photocatalysis, adsorption, separation and life science applications, significant interest has been devoted to the design and synthesis of hierarchically porous materials. The hierarchy of materials on porosity, structural, morphological, and component levels is key for high performance in all kinds of applications. Synthesis and applications of hierarchically structured porous materials have become a rapidly evolving field of current interest. A large series of synthesis methods have been developed. This review addresses recent advances made in studies of this topic. After identifying the advantages and problems of natural hierarchically porous materials, synthetic hierarchically porous materials are presented. The synthesis strategies used to prepare hierarchically porous materials are first introduced and the features of synthesis and the resulting structures are presented using a series of examples. These involve templating methods (surfactant templating, nanocasting, macroporous polymer templating, colloidal crystal templating and bioinspired process, i.e. biotemplating), conventional techniques (supercritical fluids, emulsion, freeze-drying, breath figures, selective leaching, phase separation, zeolitization process, and replication) and basic methods (sol–gel controlling and post-treatment), as well as self-formation phenomenon of porous hierarchy. A series of detailed examples are given to show methods for the synthesis of hierarchically porous structures with various chemical compositions (dual porosities: micro–micropores, micro–mesopores, micro–macropores, meso–mesopores, meso–macropores, multiple porosities: micro–meso–macropores and meso–meso–macropores). We hope that this review will be helpful for those entering the field and also for those in the field who want quick access to helpful reference information about the synthesis of new hierarchically porous materials and methods to control their structure and morphology.

/pdf/hierarchically-porous-materials-synthesis-strategies-and-568soqnq77.pdf

Hierarchically porous materials: synthesis strategies and structure design

A perfect ultra-narrow band infrared metamaterial absorber based on the all-metal-grating structure is proposed. The absorber presents a perfect absorption efficiency of over 98% with an ultra-narrow bandwidth of 0.66 nm at normal incidence. This high efficient absorption is contributed to the surface plasmon resonance. Moreover, the surface plasmon resonance-induced strong surface electric field enhancement is favorable for application in biosensing system. When operated as a plasmonic refractive index sensor, the ultra-narrow band absorber has a wavelength sensitivity 2400 nm/RIU and an ultra-high figure of merit 3640, which are much better than those of most reported similar plasmonic sensors. Besides, we also comprehensively investigate the influences of structural parameters on the sensing properties. Due to the simplicity of its geometry structure and its easiness to be fabricated, the proposed high figure of merit and sensitivity sensor indicates a competitive candidate for applications in sensing or detecting fields.

/pdf/infrared-plasmonic-refractive-index-sensor-with-ultra-high-yzce5yg79w.pdf

Infrared Plasmonic Refractive Index Sensor with Ultra-High Figure of Merit Based on the Optimized All-Metal Grating.

Evolution has provided a source of inspiration for algorithm designers since the birth of computers. The resulting field, evolutionary computation, has been successful in solving engineering tasks ranging in outlook from the molecular to the astronomical. Today, the field is entering a new phase as evolutionary algorithms that take place in hardware are developed, opening up new avenues towards autonomous machines that can adapt to their environment. We discuss how evolutionary computation compares with natural evolution and what its benefits are relative to other computing approaches, and we introduce the emerging area of artificial evolution in physical systems.

/pdf/from-evolutionary-computation-to-the-evolution-of-things-3bwwcbma3i.pdf

From evolutionary computation to the evolution of things

Computational microstructure characterization and reconstruction: Review of the state-of-the-art techniques

Concentrating photovoltaic (CPV) systems are a key step in expanding the use of solar energy. Solar cells can operate at increased efficiencies under higher solar concentration and replacing solar cells with optical devices to capture light is an effective method of decreasing the cost of a system without compromising the amount of solar energy absorbed. However, CPV systems are still in a stage of development where new designs, methods and materials are still being created in order to reach a low levelled cost of energy comparable to standard silicon based PV systems. This article outlines the different types of concentration photovoltaic systems, their various design advantages and limitations, and noticeable trends. This will include comparisons on materials used, optical efficiency and optical tolerance (acceptance angle). As well as reviewing the recent development in the most commonly used and most established designs such as the Fresnel lens and parabolic trough/dish, novel optics and materials are also suggested. The aim of this review is to provide the reader with an understanding of the many types of solar concentrators and their reported advantages and disadvantages. This review should aid the development of solar concentrator optics by highlighting the successful trends and emphasising the importance of novel designs and materials in need of further research. There is a vast opportunity for solar concentrator designs to expand into other scientific fields and take advantage of these developed resources. Solar concentrator technologies have many layers and factors to be considered when designing. This review attempts to simplify and categorise these layers and stresses the significance of comparing as many of the applicable factors as possible when choosing the right design for an application. From this review, it has been ascertained that higher concentration levels are being achieved and will likely continue to increase as high performance high concentration designs are developed. Fresnel lenses have been identified as having a greater optical tolerance than reflective parabolic concentrators but more complex homogenisers are being developed for both system types which improve multiple performance factors. Trends towards higher performance solar concentrator designs include the use of micro-patterned structures and attention to detailed design such as tailoring secondary optics to primary optics and vice-versa. There is still a vast potential for what materials and surface structures could be utilised for solar concentrator designs especially if inspiration is taken from biological structures already proven to manipulate light in nature.

/pdf/optics-for-concentrating-photovoltaics-trends-limits-and-3ddbtiv50v.pdf

Optics for concentrating photovoltaics: Trends, limits and opportunities for materials and design

Quasi-random nanostructures have attracted significant interests for photon management purposes. To optimize such patterns, typically very expensive fabrication processes are needed to create the pre-designed, subwavelength nanostructures. While quasi-random photonic nanostructures are abundant in nature (for example, in structural coloration), interestingly, they also exist in Blu-ray movie discs, an already mass-produced consumer product. Here we uncover that Blu-ray disc patterns are surprisingly well suited for light-trapping applications. While the algorithms in the Blu-ray industrial standard were developed with the intention of optimizing data compression and error tolerance, they have also created quasi-random arrangement of islands and pits on the final media discs that are nearly optimized for photon management over the solar spectrum, regardless of the information stored on the discs. As a proof-of-concept, imprinting polymer solar cells with the Blu-ray patterns indeed increases their efficiencies. Simulation suggests that Blu-ray patterns could be broadly applied for solar cells made of other materials.

/pdf/repurposing-blu-ray-movie-discs-as-quasi-random-1njubl6aor.pdf

Repurposing Blu-ray movie discs as quasi-random nanoimprinting templates for photon management

Influence of Mn doping on the microstructure and optical properties of CdS

The nanofocusing of light source was proposed and simulated using the dielectric-loaded surface plasmon polariton (SPP) model with various laterally tapered planar dielectric architectures on the top surface of the metal. By using finite-difference time-domain method, enhancement factor for the local electric field under distinctive incident polarization was analyzed with different taper apexes under various incident wavelengths and incident angles of the excitation laser. The SPP dispersion and the effect of dissipation on adiabatic nanofocusing of SPP in a sharp taper structure were used to predict the optimal taper angles of the structure and to explain the phenomena of SPP wave slowing down as it propagating toward the taper end. This SPP nanofocusing process was also experimentally realized by illuminating the structure of a tapered CdS nanoribbon deposited on the Ag surface. As the emission of the focused SPP at the taper end, the proposed plasmonic structure can be severed as a light nanosource emitter in the future optical integrated circuits.

Hybrid Plasmonic Waveguide Based on Tapered Dielectric Nanoribbon: Excitation and Focusing

Ammonium/tetraalkylammonium perfluorooctanoates [C7F15COON(CnH2n+1)4, n = 0, 1, 2, 3, 4; abbreviated as APFO, TMAPFO, TEAPFO, TPAPFO, and TBAPFO, respectively] were investigated by electrical conductivity measurements at different temperatures T. The critical micelle concentration (cmc) as a function of T showed a typical U-shaped relationship for APFO, TMAPFO, TEAPFO, and TPAPFO, similar to that for ordinary ionic surfactants. However, TBAPFO presented behavior more like that of nonionic surfactants. APFO exhibited a complicated dependence of the degree of counterion association of aggregates (β) on T, probably because of its hydrolysis in solution. Both the cmc and standard Gibbs energy of aggregation (ΔaggrG°) decreased with increasing counterion size, while the degree of counterion association (β) was found to increase with the counterion size. There was a linear relationship between ln(cmc) and the chain length of the counterions (n), suggesting that the hydrophobic chains of counterions made contrib...

Thermodynamics of Aggregation of Ammonium/Tetraalkylammonium Perfluorooctanoates: Effect of Counterions†

We report the design of reconfigurable metamolecules consisting a large array of nanowire featuring U-shaped cross section. These nanoscale metamolecules support colocalized electromagnetic resonance at optical frequencies and mechanical resonance at GHz frequencies with a deep-subdiffraction-limit spatial confinement (∼λ2/100). The coherent coupling of those two distinct resonances manifests a strong optical force, which is fundamentally different from the commonly studied forms of radiation forces, gradient forces, or photothermal induced deformation. The strong optical force acting upon the built-in compliance further sets the stage for allowing the metamolecules to dynamically change their optical properties upon the incident light. The all-optical modulation at the frequency at 1.8 GHz has thus been demonstrated experimentally using a monolayer of metamolecules. The metamolecules were conveniently fabricated using complementary metal-oxide–semiconductor-compatible metal deposition and nanoimprinting ...

Gigahertz All-Optical Modulation Using Reconfigurable Nanophotonic Metamolecules.

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