Cassandra T. Eagle
East Tennessee State University
7 Papers
33 Citations
Cassandra T. Eagle is an academic researcher from East Tennessee State University. The author has contributed to research in topics: Nitrile & Coordination sphere. The author has an hindex of 3, co-authored 7 publications.
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Papers
Synthesis, structural studies and catalytic activity of a series of dioxidomolybdenum(VI)-thiosemicarbazone complexes
Satabdi Roy,Satabdi Roy,Saswati,Sudhir Lima,Sarita Dhaka,Sarita Dhaka,Mannar R. Maurya,Rama Acharyya,Cassandra T. Eagle,Rupam Dinda +9 more
TL;DR: In this paper, the reaction of the thiosemicarbazone ligands, [4-(p-bromophenyl)thIosemicarazone of salicylaldehyde (H2L1), 4-(P-X-phenyl)-thIosifidis-thIoSmdrazone (X-Pphenyl), and 4-(pchlorophenyl),thIoSmdrasone of o-vanillin (O-H2O), to a series of new oxidomolybdenum(
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Tetrakis[μ-N-(2,4,6-trimethylphenyl)acetamidato]-κ4N:O;κ4O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh)
TL;DR: The title structure, [Rh2(C11H14NO)4(C7H5N)2], contains a dinuclear Rh complex of point symmetry -4 with an Rh—Rh unit and two benzonitrile ligands located in special positions along the twofold axis passing through -4.
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cis-Tetrakis(μ-N-phenylacetamidato)-κ4N:O;κ4O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh)
TL;DR: The axial nitrile ligand completes the distorted octahedral coordination sphere and shows a non-linear coordination with an Rh—N—C bond angle of 167.14 (15)°, while the N-C bond length is 1.135”(3) Å.
4
(3-Methylbenzonitrile-κN)tetrakis(μ-N-phenylacetamidato)-κ4N:O;κ4O:N-dirhodium(II)(Rh—Rh)
TL;DR: In the title compound, [Rh2(C 8H8NO)4(C8H7N)], the four acetamidate ligands bridging the dirhodium core are arranged in a 2,2-trans manner, with one RhII atom is five-coordinate, in a distorted pyramidal geometry, while the other is six- coordinate, with a disorted octahedral geometry.
3
(3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ4N:O;1:2κ4O:N-dirhodium(II)(Rh—Rh)
TL;DR: The complex molecule of the title compound, [Rh2{N(C6H5)COCH3}4(NCC7H7)], has crystallographically-imposed mirror symmetry and shows a nonlinear coordination, with an Rh—N—C bond angle of 162.8 (5)°.