Aurélie Macé
University of Rennes
20 Papers
113 Citations
Aurélie Macé is an academic researcher from University of Rennes. The author has contributed to research in topics: Chemistry & Sigmatropic reaction. The author has an hindex of 8, co-authored 18 publications.
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Papers
An enantiopure cyclometallated iridium complex displaying long-lived phosphorescence both in solution and in the solid state.
Aurélie Macé,Nora Hellou,Joanna Hammoud,Clothilde Martin,Etienne S. Gauthier,Ludovic Favereau,Thierry Roisnel,Elsa Caytan,Ghassan Nasser,Nicolas Vanthuyne,J. A. Gareth Williams,Fabienne Berrée,Bertrand Carboni,Jeanne Crassous +13 more
TL;DR: In this article, a cyclometallated iridium complex bearing a helicenic :C^C+ and two :N^C− dfppy (2−(2,4−difluorophenyl)‐pyridyl) ligands was prepared.
[3,3]-Sigmatropic rearrangement of boronated allylcyanates: a new route to α-aminoboronate derivatives and trisubstituted tetrahydrofurans.
Sabrina Touchet,Aurélie Macé,Thierry Roisnel,François Carreaux,Alexandre Bouillon,Bertrand Carboni +5 more
TL;DR: Hydrogenation gave the corresponding α-aminoboronates derivatives while addition of aldehydes afforded homoallylic alcohols, (tetrahydrofuran-2-yl)carbamate, ether, or urea derivatives.
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[3,3]‐Sigmatropic Rearrangement/Allylboration/Cyclization Sequence: Enantioenriched Seven‐Membered‐Ring Carbamates and Ring Contraction to Pyrrolidines
Aurélie Macé,Sabrina Touchet,Sabrina Touchet,Patricia Andres,Patricia Andres,Fernando P. Cossío,Vincent Dorcet,François Carreaux,Bertrand Carboni +8 more
TL;DR: A computational study provides evidence on the feasibility of the proposed mechanism of this unusual ring contraction and an unprecedented rearrangement of 5-acetoxy-7-aryl or styryl derivatives led to tetrasubstituted pyrrolidines.
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Tandem reactions involving 1-silyl-3-boryl-2-alkenes. New access to (Z)-1-fluoro-1-alkenes, allyl fluorides, and diversely α-substituted allylboronates
Aurélie Macé,Fabien Tripoteau,Qian Zhao,Eric Gayon,Emmanuel Vrancken,Jean-Marc Campagne,Bertrand Carboni +6 more
TL;DR: The reactions of 1-silyl-3-boryl-2-alkenes with various electrophilic reagents have been investigated as new routes to α-substituted allylboronates to illustrate the synthetic potential of these γ- borylallylsilanes.
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The Allyl Cyanate/Isocyanate Rearrangement: An Efficient Tool for the Stereocontrolled Formation of Allylic C–N Bonds
Pierre-Antoine Nocquet,Sylvain Henrion,Aurélie Macé,Bertrand Carboni,Jose Manuel Villalgordo,François Carreaux +5 more
TL;DR: The allyl cyanate/isocyanate rearrangement as mentioned in this paper is a popular method for the synthesis of complex nitrogen-containing molecules such as natural products, and it usually occurs at or below ambient temperature with no need to use any metal catalyst, in a stereospecific way, and with complete transfer of chirality.
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