Arnold L. Rheingold
University of California, San Diego
1432 Papers
18.7K Citations
Arnold L. Rheingold is an academic researcher from University of California, San Diego. The author has contributed to research in topics: Chemistry & Ligand. The author has an hindex of 75, co-authored 1392 publications. Previous affiliations of Arnold L. Rheingold include Scripps Research Institute & University of Cambridge.
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Papers
Coordinated homoatomic polyorganophosphorus catenates. The crystal structure and molecular geometry of Fe2(CO)6(PCH3)4 and Fe2(CO)6(PC6H5)4
TL;DR: Les deux complexes du titre cristallisent dans le systeme monoclinique, groupe P2 1 /c Coordination pyramidale tetraedrique deformee autour des atomes metalliques dans les deux cas Spectres RMN as discussed by the authors.
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Luminescent Tris(8-hydroxyquinolates) of Bismuth(III)
TL;DR: Electronic structure DFT calculations support trends seen in the experimental results with a HOMO-LUMO gap of 2.156 eV calculated for the monomer that is significantly larger than those for the dimers.
Chemistry at the Alkyne–Carbene Intersection: A Metallacyclobutene−η3-Vinylcarbene Equilibration
TL;DR: The structure of the η(3)-vinylcarbene complex was elucidated by spectroscopy, HRMS, and ab initio computations and led to the first observation of metallacyclobutene-η( 3)-vinelcarbene equilibration.
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Stabilization of a large arsenic-oxygen heterocycle via metal coordination. The synthesis and x-ray crystal structure of [Mo(CO)3]2[cyclo-(MeAsO)6]
TL;DR: Le compose du titre cristallise dans le systeme orthorhombique, groupe Cmca as discussed by the authors, groupe de CmCA (CmCA).
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