Andrei V. Yermalayeu
University of Rostock
24 Papers
201 Citations
Andrei V. Yermalayeu is an academic researcher from University of Rostock. The author has contributed to research in topics: Ionic liquid & Vaporization. The author has an hindex of 13, co-authored 24 publications. Previous affiliations of Andrei V. Yermalayeu include Belarusian State University.
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Papers
Making sense of enthalpy of vaporization trends for ionic liquids: new experimental and simulation data show a simple linear relationship and help reconcile previous data
Sergey P. Verevkin,Dzmitry H. Zaitsau,Vladimir N. Emel’yanenko,Andrei V. Yermalayeu,Christoph Schick,Hongjun Liu,Edward J. Maginn,Safak Bulut,Ingo Krossing,Roland S. Kalb +9 more
TL;DR: New experimental data, based on the concurring results from quartz crystal microbalance, thermogravimetric analyses, and molecular dynamics simulation have revealed a clear linear dependence of IL vaporization enthalpies on the chain length of the alkyl group on the cation.
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Thermodynamics of Imidazolium-Based Ionic Liquids Containing PF6 Anions
Dzmitry H. Zaitsau,Andrei V. Yermalayeu,Vladimir N. Emel’yanenko,Simon N. Butler,Thomas J. S. Schubert,Sergey P. Verevkin +5 more
TL;DR: An absence of decomposition of ILs in experimental conditions was determined by the attenuated total reflection-infrared spectroscopy and the consistency of the experimental results within the homologous series was established through enthalpy and entropy analyses of the liquid and gas phases as well as by molecular dynamics simulations.
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Structure–Property Relationships in Ionic Liquids: A Study of the Anion Dependence in Vaporization Enthalpies of Imidazolium‐Based Ionic Liquids
Dzmitry H. Zaitsau,Koichi Fumino,Vladimir N. Emel’yanenko,Andrei V. Yermalayeu,Ralf Ludwig,Sergey P. Verevkin +5 more
TL;DR: A simple group-contribution method is developed for prediction of vaporization enthalpies of alkyl imidazolium-based ILs and a linear relation between enthalpy and the intermolecular vibrational frequencies is observed and suggested for calculation of unknown ILs.
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Does alkyl chain length really matter? Structure-property relationships in thermochemistry of ionic liquids
Sergey P. Verevkin,Dzmitry H. Zaitsau,Vladimir N. Emel’yanenko,Ricardas V. Ralys,Andrei V. Yermalayeu,Christoph Schick +5 more
TL;DR: In this article, a combination of DSC with quantum chemical calculations presents an indirect way to study thermodynamics of ionic liquids, and the indirect procedure for vaporization enthalpy was validated with the direct experimental measurements by using thermogravimetry.
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Structure-property relationships in ILs: A study of the alkyl chain length dependence in vaporisation enthalpies of pyridinium based ionic liquids
Dzmitry H. Zaitsau,Andrei V. Yermalayeu,Vladimir N. Emel’yanenko,Sergey P. Verevkin,Urs Welz-Biermann,Thomas J. S. Schubert +5 more
TL;DR: In this article, the enthalpies of pyridinium-based ionic liquids with bis(trifluoromethylsulfonyl)imide anion [C n Py][NTf2] (n = 2, 3, 4, 5, and 6) have been determined with the quartz crystal microbalance technique combined with the Langmuir evaporation.
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