Andreas Zanin
Braunschweig University of Technology
7 Papers
74 Citations
Andreas Zanin is an academic researcher from Braunschweig University of Technology. The author has contributed to research in topics: Diphosphene & Trichlorosilane. The author has an hindex of 4, co-authored 7 publications.
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Papers
Erste Reaktionen an der P=C- und an der P–P-Bindung des neuen P-Phosphanylphosphaalkens 1-Bis(trimethylsilyl)methyliden-2,2-diisopropyldiphosphan
TL;DR: The P-C double bond of 2 can be protected reversibly by a cycloaddition with cyclopentadiene resulting in the formation of a P-phosphanorbornen derivative.
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Novel trichlorosilylation and trichlorogermylation of a P-chlorophosphaalkene leading to functionally substituted diphosphenes
TL;DR: The reactions of P-chlorobis(trimethylsilyl)methylenephosphane with hexachlorodisilane or with dichlorogermylene-dioxane afford the new Si-functionalised ditrisyldiphosphene derivative [(Me 3 Si) 2 (Cl 3 Si)-CP] 2 and the related trichloroglomermyl diphosphenes.
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Extension of the Benkeser reaction to the reductive trichlorosilylation of main group element chlorides
TL;DR: In this article, double trichlorosilylation was used to obtain cyclophosphanes (RP) n 5 (thus 4a and 4e could not be isolated in a pure state) or to trichodorosilylphosphanes RP(H)SiCl 3 6.
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Reactions of Silicon–Silicon Bonds, VI. Reductive Trichloroslilylation Reactions Leading to Alkyl‐ and Dialkylaminobis(trichlorosilyl)phosphanes
Lutz‐Peter Müller,Andreas Zanin,Wolf-Walther du Mont,Jörg Jeske,Reiner Martens,Peter G. Jones +5 more
TL;DR: The first aminobis(trichlorosilyl)phosphane was determined by X-ray crystallography as mentioned in this paper, which contains a phosphorus atom in a pyramidal environment surrounded by two silicon atoms and a planar nitrogen atom.
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Dichlorosilylene Transfer to a P‐Fluorophosphaalkene: The Route to a C‐Dichlorofluorosilyl‐Functionalized Dialkyldiphosphene
Cristina Mitrofan,Thorsten Gust,Andreas Zanin,Roxana M. Bîrzoi,Peter G. Jones,Wolf-W. du Mont,Satoko Hayashi,Waro Nakanishi,Heinrich Marsmann +8 more
TL;DR: In this paper, the trichlorosilylgermane Me3GeSiCl3 and the unsymmetric disilane Me3SiSiCl 3 with the P-fluorophosphaalkene (Me3Si)2C=PF were detected by 31P-NMR.
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