Aisling Roper
5 Papers
Aisling Roper is an academic researcher. The author has contributed to research in topics: Ligand (biochemistry) & Metathesis. The author has an hindex of 1, co-authored 1 publications.
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Papers
Taming Heavier Group 14 Imine Analogues: Accessing Tin Nitrogen [Sn=N] Double Bonds and their Cycloaddition/Metathesis Chemistry
Malte Fischer,Matthew M. D. Roy,Lewis L Wales,Mathias Ellwanger,Caitilín McManus,Aisling Roper,Andreas Heilmann,Simon Aldridge +7 more
TL;DR: In this article , a systematic study to access stable stannaimines is reported, by combining different heteroleptic stannylenes with a range of organic azides, which yield the putative tin nitrogen double bond, but is directly followed by 1,2 silyl migration to give SnII systems featuring bulky silylamido ligands.
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Reversible [4 + 1] Cycloaddition of Arenes by a "Naked" Acyclic Aluminyl Compound.
Debotra Sarkar,Petra Vasko,Aisling Roper,Agamemnon E Crumpton,Matthew M. D. Roy,Liam Griffin,Charlotte Bogle,Simon Aldridge +7 more
TL;DR: The first naked acyclic aluminyl complex is synthesized and shown to catalyze reversible [4 + 1] cycloaddition of Arenes.
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Synthesis, Isolation, and Reactivity Studies of 'Naked' Acyclic Gallyl and Indyl Anions.
Debotra Sarkar,Petra Vasko,Tihomir Gluharev,Liam Griffin,Charlotte Bogle,Job J C Struijs,Jianqin Tang,Aisling Roper,Agamemnon E Crumpton,Simon Aldridge +9 more
- 22 May 2024
TL;DR: Synthesis and reactivity studies of 'naked' acyclic gallyl and indyl anions, showcasing the first O-ligated systems and their nucleophilic reactivity.
A nucleophilic beryllyl complex via metathesis at [Be-Be]2.
TL;DR: Researchers develop a nucleophilic beryllyl complex via metathesis, yielding a complex with a polarized Be-Be bond, and demonstrate its ability to transfer the 'beryllyl' anion to organic substrates, revealing similarities with boron's homo-elemental bonding.
Bis(aluminyl)magnesium: a source of nucleophilic or radical aluminium-centred reactivity.
Liam Griffin,Mathias A Ellwanger,Jonathon Clark,William Myers,Aisling Roper,Andreas Heilmann,Simon Aldridge +6 more
- 27 Mar 2024
TL;DR: Mg[Al(NON)]2 exhibits nucleophilic aluminium-centred reactivity with polar substrates and radical reactivity under photolytic conditions, with dispersion interactions influencing its non-linear geometry, and acting as a four-electron reservoir in reductive de-fluorination of SF6.