Carrier-Based Ion-Selective Electrodes and Bulk Optodes. 1. General Characteristics.

Lipophilic and immobilized anionic additives in solvent polymeric membranes of cation-selective chemical sensors

A cobalt(II)-selective PVC membrane based on a Schiff base complex of N,N′-bis(salicylidene)-3,4-diaminotoluene

Over the last 30 years, IUPAC published several documents with the goal of achieving standardized nomenclature and methodology for potentiometric ion-selective electrodes (ISEs). The ISE vocabulary was formulated, measurement protocols were suggested, and the selectivity coefficients were compiled. However, in light of new discoveries and experimental possibilities in the field of ISEs, some of the IUPAC recommendations have become outdated. The goal of this technical report is to direct attention to ISE practices and the striking need for updated or refined IUPAC recommendations which are consistent with the state of the art of using macro- and microfabricated planar microelectrodes. Some of these ISE practices have never been addressed by IUPAC but have gained importance with the technological and theoretical developments of recent years. In spite of its recognized importance, a generally acceptable revision of the current IUPAC recommendations is far beyond the scope of this work.

/pdf/performance-evaluation-criteria-for-preparation-and-2rlqr6ou6m.pdf

Performance evaluation criteria for preparation and measurement of macro- and microfabricated ion-selective electrodes (IUPAC Technical Report)

A cerium(III) selective polyvinyl chloride membrane sensor based on a Schiff base complex of N,N'-bis[2-(salicylideneamino)ethyl]ethane-1,2-diamine.

Lipophilic salts consisting of either lipophilic cations and hydrophilic anions or hydrophilic cations and lipophilic anions act in liquid membranes as anion exchangers and cation exchangers, respectively. A large number of corresponding membrane electrodes have been described in the literature (for reviews see [2, 4, 6]). A comparison of the ion selectivities obtained with a variety of different anion exchangers corroborates the theoretical prediction that the structure of the ion exchanger molecules involved should have only minor influences on the observable ion selectivities [2,4–7]. The selectivity sequences correlate nicely with the sequence of the free energies of hydration of the ions (cf. [4–5]).

Effects of Lipophilic Charged Sites on the Electromotive Behavior of Liquid Membrane Electrodes

Lipophilic salts as membrane additives and their influence on the properties of macro- and micro-electrodes based on neutral carriers

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Effects of Lipophilic Charged Sites on the Electromotive Behavior of Liquid Membrane Electrodes

Lipophilic salts as membrane additives and their influence on the properties of macro- and micro-electrodes based on neutral carriers